Search results for "Azido ligand"

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The azido ligand: a useful tool in designing chain compounds exhibiting alternating ferro- and antiferro-magnetic interactions

1997

A one-pot reaction of NiII 1, CoII 2, FeII 3 and MnII 4 with 2,2A-bipyridine (bipy) and azide in water leads to [M(bipy)(N3)2]n chains where the metal ion is alternatively bridged by double end-on (EO) and end-to-end (EE) azido bridges; theoretical analysis of the variable-temperature magnetic susceptibility data of 1 and 4 reveals the occurrence of intrachain alternating ferro- (through EO) and antiferro-magnetic (through EE) interactions. Julve Olcina, Miguel, Miguel.Julve@uv.es ; Lloret Pastor, Francisco, Francisco.Lloret@uv.es ; Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es

Azido ligand ; Ferro-magnetic ; Antiferro-magnetic ; BipyrineStereochemistryUNESCO::QUÍMICABipyrine:QUÍMICA [UNESCO]CatalysisMetalchemistry.chemical_compoundChain (algebraic topology)Ferro-magneticMaterials ChemistryChemistryLigandUNESCO::QUÍMICA::Química inorgánicaMetals and AlloysAzido ligandGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]Magnetic susceptibilitySurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyvisual_artAntiferro-magneticCeramics and Compositesvisual_art.visual_art_mediumAzide

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